Subjects: Optics >> Quantum optics submitted time 2023-02-19
Abstract: To develop highly sensitive, stable and repeatable surface-enhanced Raman scattering (SERS) substrates is crucial for analytical detection, which is a challenge for traditional metallic structures. Herein, by taking advantage of the high surface activity of 1T' transition metal telluride, we have fabricated high-density gold nanoparticles (AuNPs) that are spontaneously in-situ prepared on the 1T' MoTe2 atomic layers via a facile method, forming a plasmonic-2D material hybrid SERS substrate. This AuNP formation is unique to the 1T' phase, which is repressed in 2H MoTe2 with less surface activity. The hybrid structure generates coupling effects of electromagnetic and chemical enhancements, as well as excellent molecule adsorption, leading to the ultrasensitive (4*10^-17 M) and reproducible detection. Additionally, the immense fluorescence and photobleaching phenomena are mostly avoided. Flexible SERS tapes have been demonstrated in practical applications. Our approach facilitates the ultrasensitive SERS detection by a facile method, as well as the better mechanistic understanding of SERS beyond plasmonic effects.
Peer Review Status:Awaiting Review
Subjects: Optics >> Quantum optics submitted time 2023-02-19
Abstract: Generally, a superconducting nanowire single-photon detector (SNSPD) is composed of wires with a typical width of ~100 nm. Recent studies have found that superconducting strips with a micrometer-scale width can also detect single photons. Compared with the SNSPD, the superconducting microstrip single-photon detector (SMSPD) has smaller kinetic inductance, higher working current, and lower requirement in fabrication accuracy, providing potential applications in the development of ultra-large active area detectors. However, the study on SMSPD is still in its infancy, and the realization of its high-performance and practical use remains an opening question. This study demonstrates a NbN SMSPD with a saturated system detection efficiency (SDE) of ~92.2% at a dark count rate of ~200 cps, a polarization sensitivity of ~1.03, and a minimum timing jitter of ~48 ps, at the telecom wavelength of 1550 nm when coupled with a single mode fiber and operated at 0.84 K. Furthermore, the detector's SDE is over 70% when operated at a 2.1-K closed-cycle cryocooler.
Peer Review Status:Awaiting Review
Subjects: Optics >> Quantum optics submitted time 2023-02-19
Abstract: C-H bond activation enables the facile synthesis of new chemicals. While C-H activation in short-chain alkanes has been widely investigated, it remains largely unexplored for long-chain organic molecules. Here, we report light-driven C-H activation in complex organic materials mediated by 2D transition metal dichalcogenides (TMDCs) and the resultant solid-state synthesis of luminescent carbon dots in a spatially resolved fashion. Through the first-principle calculations, we unravel that the defects and oxidized states in 2D TMDCs lead to efficient C-H activation and chemical reaction. Furthermore, we exploit the light-controlled point-and-shoot chemical reaction for versatile carbon dot patterning and optical encoding of encrypted information. Our results will shed light on 2D materials for C-H activation in a variety of organic compounds for applications in organic chemistry, photonic materials, and environmental remediation.
Peer Review Status:Awaiting Review
Subjects: Optics >> Quantum optics submitted time 2023-02-19
Abstract: Faint light spectroscopy has many important applications such as fluorescence spectroscopy, lidar and astronomical observations. However, long measurement time limit its application on real-time measurement. In this work, a photon counting reconstructive spectrometer combining metasurfaces and superconducting nanowire single photon detectors (SNSPDs) was proposed. A prototype device was fabricated on a silicon on isolator (SOI) substrate, and its performance was characterized. Experiment results show that this device support spectral reconstruction of mono-color lights with a resolution of 2 nm in the wavelength region of 1500 nm ~ 1600 nm. The detection efficiency of this device is 1.4% ~ 3.2% in this wavelength region. The measurement time required by this photon counting reconstructive spectrometer was also investigated experimentally, showing its potential to be applied in the scenarios requiring real-time measurement.
Peer Review Status:Awaiting Review
Subjects: Optics >> Quantum optics submitted time 2023-02-19
Abstract: High-speed polarization management is highly desirable for many applications, such as remote sensing, telecommunication, and medical diagnosis. However, most of the approaches for polarization management rely on bulky optical components that are slow to respond, cumbersome to use, and sometimes with high drive voltages. Here, we overcome these limitations by harnessing photonic integrated circuits based on thin-film lithium niobate platform. We successfully realize a portfolio of thin-film lithium niobate devices for essential polarization management functionalities, including arbitrary polarization generation, fast polarization measurement, polarization scrambling, and automatic polarization control. The present devices feature ultra-fast control speed, low drive voltages, low optical losses and compact footprints. Using these devices, we achieve high fidelity polarization generation with a polarization extinction ratio up to 41.9 dB, fast polarization scrambling with a scrambling rate up to 65 Mrad/s, and endless polarization control with a tracking speed up to 10 Krad/s, all of which are best results in integrated optics. The demonstrated devices unlock a drastically new level of performance and scales in polarization management devices, leading to a paradigm shift in polarization management.
Peer Review Status:Awaiting Review